Hi there, I'm always looking for the latest bootleg superheroes mini-figures and now that it looks like Decool is no longer producing anymore, I thought it would be a good time to list all of the sets that I know of. This catalog was the latest one i could find on the internet, but it doesn't show the newest big figs or the green arrow set.
Most Decool super heroes mini-figures come in sets of 6, but some come in sets of 4 and 9 also. Big figs are listed individually or in sets of 3. If you managed to collect every one of the Decool superhero mini-figures you'd have 137 of them. I'll start with the most current series and work backwards chronologically. If the bigfig or mini-figure set is in my collection, I'll put a link to my review of it.
0232-0237 Green Arrow set of 6
0231 Iron Man MK38 Bigfig
0230 Gorilla Grodd Bigfig
0229 Darkseid Bigfig
0217-0222 Age of Ultron set of 6
0211-0216 DC Superheroes set of 6
0205-0210 Avengers set of 6
0199-0204 DC Superheroes set of 6
0198 Groot Bigfig
0192-0197 DC/Marvel Superheroes set of 6
0191 Juggernaut Bigfig
0190 Rhino Bigfig
0184-0189 Batman/Xmen Superheroes set of 6
0183 Green Goblin Bigfig
0182 Venom Bigfig
0181 Hulkbuster Bigfig
0175-0180 Guardians of the Galaxy set of 6
0169-0174 Marvel Superheroes set of 6
0160-0168 Iron Man set of 9
0156-0159 Future Foundation set of 4
0153-0155 The Thing Bigfig set of 3
0147-0152 Marvel Superheroes and Joker set of 6
0144-0146 Hulk Bigfig set of 3
0140-0143 Fantastic Four set of 4
0134-0139 Marvel/DC Superheroes set of 6
0128-0133 DC Superheroes and Dr. Doom set of 6
0122-0127 Iron Man set of 6
0116-0121 Marvel/Dc Superheroes set of 6
0110-0115 Iron Man set of 6
0101-0109 Marvel/DC Superheroes set of 9
Note: Prior to Decool's production of Marvel and DC Superheroes mini-figures, they were mainly issuing a lot of Ninja and Ninja turtle mini-figures. Their numbering scheme for those sets was inconsistent. At some point I might try to list them, but for now I'm focusing just on the Super heroes mini-figs.